Almost all systems have vents located in the discharge piping of the baseboard heater that you can see when you take the cover off of the heater. I assume you looked there given your knowledge level.
That said, there are a few systems out there with no vents. What are the safeties set at (normally 30 psig)? What do you normally run the pressure at? I would try the easy way first:
###1###
Run the pressure up as high as you are comfortable. This might be 25 or 26# or so. I wouldn't run it up this high if I suspect corroded piping in the system that may not take the abuse.
Running the pressure higher will squeeze the air bubble in the baseboard heater and possibly allow some water flow through the unit. If you can make this happen, the water will entrain the air and carry it down to the vent in the basement regardless of the size of the pump.
If this is working, you will run the pressure up and then come back later. The pressure should have come back down on it's own somewhat because of the air that has left the system. If you still have no heat, run the pressure back up.
If the pressure stays high and this procedure doesn't restore heat, then:
###2###
Check the zone valves. Push the manual open lever. Do you hear flow? Does the unit provide heat? (this will only work if the circulating pump is running) Problems related to zone valves can be the zone valve motor, the valve itself may by locked up, the transformer used for control power may be bad, the thermostat could be bad, or there could be a bad circuit board. Replace part as necessary.
I've listed the zone valve check as #2, but you could do it before trying to run the pressure up if it's easier with your system. Do whichever you suspect or what is easiest first.
When you are done, put the pressure back to normal. Normal pressure should be 0.433 X the height of the system in feet. Then add 3 to 5 pounds for a margin for error.
If that doesn't work:
###3###
Check the vent in the basement. Are you sure it's working? If it isn't, the air in the system will accumulate at the top of the system. This air may normally be entrained and carried down to the automatic vent. If the automatic vent doesn't work, the air will just be carried back to the top of the system.
If you aren't sure, replacing this will probably involve unscrewing it and screwing a new one in, which would be easier than sweating new manual valves in at the baseboard heaters.
After replacing the automatic vent, repeat step #1.
If this doesn't work:
###4###
Is there only one circulating pump in the system? My house has 5, and they aren't all right at the boiler. Make sure you know how many there are and that they all work when they are supposed to. Make sure you are hearing flow when any of the pumps are on.
Or:
###5###
Give up and sweat in manual bleeders. Hopefully one of the above procedures will save you from this, although sweating in the bleeders isn't that difficult anyway.
-Reed
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